Excerpt from Theory of Heat

The aim of this book is to exhibit the scientific connexion of the various steps by which our knowledge of the phenomena of heat has been extended. The first of these steps is the invention of the thermometer, by which the registration and comparison of temperatures is rendered possible. The second step is the measurement of quantities of heat, or Calorimetry. The whole science of heat is founded on Thermometry and Calorimetry, and when these operations are understood we may proceed to the third step, which is the investigation of those relations between the thermal and the mechanical properties of substances which form the subject of Thermodynamics The whole of this part of the subject depends on the consideration of the Intrinsic Energy of a system of bodies, as depending on the temperature and physical state, as well as the form, motion, and relative position of these bodies. Of this energy, however, only a part is available for the purpose of producing mechanical work, and though the energy itself is indestructible, the available part is liable to diminution by the action of certain natural processes, such as conduction and radiation of heat, friction, and viscosity.

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